|
|
Biodiesel is an alternative to
petroleum-based diesel fuel made from renewable resources such
as vegetable oils, animal fats, or algae. It has very similar
combustion properties to petroleum diesel, and can replace it in
current uses. However, it is most often used as an additive to
petroleum diesel, improving the low lubricity of pure ultra low
sulfur petrodiesel fuel. It is one of the most realistic
candidates to replace fossil fuels as the world's primary
transportation energy source, because it is a renewable fuel
that can replace petrodiesel in current engines and can be
transported and sold using today's infrastructure. A growing
number of fuel stations are making biodiesel available to
consumers, and a growing number of large transportation fleets
use some proportion of biodiesel in their fuel.
Biodiesel is non-flammable, and in contrast to petroleum diesel
it is non-explosive, with a flash point of 150°C for biodiesel
as compared to 64°C for petrodiesel. Unlike petrodiesel, it is
biodegradable and non-toxic, and it significantly reduces toxic
and other emissions when burned as a fuel. Chemically, it is a
fuel comprised of a mix of mono-alkyl esters of long chain fatty
acids. The most common form uses methanol to produce methyl
esters, though ethanol can be used to produce an ethyl ester
biodiesel. A lipid transesterification production process is
used to convert the base oil to the desired esters and remove
free fatty acids. A byproduct of the process is the production
of glycerol.
Currently, biodiesel is more expensive to produce than petroleum
diesel, which appears to be the primary factor keeping it from
being in more widespread use. Current worldwide production of
vegetable oil and animal fat is not enough to replace liquid
fossil fuel use. Some environmental groups, notably NRDC object
to the vast amount of farming and the resulting
over-fertilization, pesticide use, and land use conversion that
would be needed to produce the additional vegetable oil.
Transesterification of a vegetable oil was conducted as early as
1853, by scientists E. Duffy and J. Patrick, many years before
the first diesel engine became functional.
Rudolf Diesel's diesel engine, a
single 10 ft (3 m) iron cylinder with a flywheel at its base,
ran on its own power for the first time in Augsburg, Germany on
August 10, 1893. Diesel later demonstrated his engine at the
World Fair in Paris, France in 1900. This engine stood as an
example of Diesel's vision because it was powered by peanut
oil—a biofuel. He believed that the utilization of a biomass
fuel was the real future of his engine. In a 1912 speech, Rudolf
Diesel said, "the use of vegetable oils for engine fuels may
seem insignificant today, but such oils may become, in the
course of time, as important as petroleum and the coal-tar
products of the present time."
During the 1920s, diesel engine manufacturers altered their
engines to utilize the lower viscosity of the fossil fuel (petrodiesel)
rather than vegetable oil, a biomass fuel. The petroleum
industries were able to make inroads in fuel markets because
their fuel was much cheaper to produce than the biomass
alternatives. The result was, for many years, a near elimination
of the biomass fuel production infrastructure. Only recently
have environmental impact concerns and a decreasing cost
differential made biomass fuels such as biodiesel a growing
alternative.
In the 1990s, France launched the local production of biodiesel
fuel (known locally as diester) obtained by the
transesterification of rapeseed oil. It is mixed to the
proportion of 5% into regular diesel fuel, and to the proportion
of 30% into the diesel fuel used by some captive fleets (public
transportation). Renault, Peugeot and other manufacturers have
certified truck engines for use with up to this partial
biodiesel. Experiments with 50% biodiesel are underway.
Many environmentalists and farmers have turned to making their
own home brew biodiesel by using either their excess crops or
used oil from restaurants, not only are they helping the
environment they are also saving money.
|